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JEE Main 20236 AprilMorning Shift
Exam
JEE Main
Year
2023
Date
6 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Solid State

JEE Main 2023 · 6 April · Morning Shift · Chemistry · Solid State

A compound is formed by two elements X and Y . The element Y forms...

A compound is formed by two elements XX and Y.Y . The element YY forms cubic close packed arrangement and those of element XX occupy one third of the tetrahedral voids. What is the formula of the compound?

Options

  1. AX2Y3{X}_{2}{Y}_{3}
  2. BX3Y2{X}_{3}{Y}_{2}
  3. CX3Y{X}_{3}Y
  4. DXY3{XY}_{3}

Correct answer

A. X2Y3{X}_{2}{Y}_{3}

Step-by-step solution

Atoms of Element YY, are present in cubic close packing. In cubic close packing the number of atoms per unit cell is 44.

So, the effective number of element YY, per unit cell is 44

Element XX, are present at one third of the tetrahedral voids.

Number of tetrahedral void =Twice the number of atoms in unit cell

Number of atoms of Element XX are present unit cell =13×8=83= \dfrac{1}{3} \times 8 = \dfrac{8}{3}

X:Y83:42:3X: Y\dfrac{8}{3}: 42: 3

Formula of the compound =X2Y3= {X}_{2}{Y}_{3}

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