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JEE Main 202325 JanuaryEvening Shift
Exam
JEE Main
Year
2023
Date
25 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Solutions

JEE Main 2023 · 25 January · Evening Shift · Chemistry · Solutions

What is the mass ratio of ethylene glycol ( C _ 2 H _ 6 O _ 2 ,...

What is the mass ratio of ethylene glycol (C2H6O2{C}_{2}{H}_{6}{O}_{2}, molar mass =62g/mol= 62g / mol) required for making 500g500g of 0.250 . 25 molal aqueous solution and 250mL250mL of 0.250 . 25 molar aqueous solution?

Options

  1. A1:11: 1
  2. B3:13: 1
  3. C2:12: 1
  4. D1:21: 2

Correct answer

C. 2:12: 1

Step-by-step solution

The molality of aqueous ethylene glycol solution = 0.25 m

Mass of ethylene glycol required for 1000 g water = 624=15.5gm\dfrac{62}{4} = 15 . 5gm

Mass of solution = 1015.5 gm

Mass of ethylene glycol in 500 gm solution =15.5×5001015.5=7.63gm= \dfrac{15 . 5 \times 500}{1015 . 5} = 7 . 63gm

Assuming density of solution as 1 gm/mL.

Mass of ethylene glycol in 250 mL =7.632=3.815gm= \dfrac{7 . 63}{2} = 3 . 815gm

Mass ratio of ethylene glycol for making 500 gm of 0.25 m solution and 250 mL of 0.25 m solution = 2:12: 1

So, the correct option is C

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