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JEE Main 20266 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
6 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Some Basic Concepts of Chemistry

JEE Main 2026 · 6 April · Evening Shift · Chemistry · Some Basic Concepts of Chemistry

Which of the following contain the same number of atoms ? (Given :...

Which of the following contain the same number of atoms ? (Given : Molar mass in g mol−1^{-1} of H, He, O and S are 1,4,161, 4, 16 and 3232 respectively)
A. 22 g of O2_2 gas
B. 44 g of SO2_2 gas
C. 14001400 mL of O2_2 at STP
D. 0.050.05 L of He at STP
E. 0.06250.0625 mol of H2_2 gas
Choose the correct answer from the options given below :

Options

  1. AA and B only
  2. BB and C only
  3. CC and D only
  4. DA, C and E only

Correct answer

D. A, C and E only

Step-by-step solution

Number of atoms is calculated as the product of the number of moles, atomicity, and Avogadro's number (NAN_A).

For A: Moles of O2=232=116_2=\dfrac{2}{32} = \dfrac{1}{16} mol. Atomicity of O2_2 is 22.
Number of atoms = 116×2×NA=18NA\dfrac{1}{16} \times 2 \times N_A = \dfrac{1}{8} N_A

For B: Moles of SO2=464=116_2=\dfrac{4}{64} = \dfrac{1}{16} mol. Atomicity of SO2_2 is 33.
Number of atoms = 116×3×NA=316NA\dfrac{1}{16} \times 3 \times N_A = \dfrac{3}{16} N_A

For C: Moles of O2_2 at STP = 140022400=116\dfrac{1400}{22400} = \dfrac{1}{16} mol. Atomicity of O2_2 is 22.
Number of atoms = 116×2×NA=18NA\dfrac{1}{16} \times 2 \times N_A = \dfrac{1}{8} N_A

For D: Moles of He at STP = 0.0522.4=1448\dfrac{0.05}{22.4} = \dfrac{1}{448} mol. Atomicity of He is 11.
Number of atoms = 1448×1×NA=1448NA\dfrac{1}{448} \times 1 \times N_A = \dfrac{1}{448} N_A

For E: Moles of H2=0.0625=116_2=0.0625 = \dfrac{1}{16} mol. Atomicity of H2_2 is 22.
Number of atoms = 116×2×NA=18NA\dfrac{1}{16} \times 2 \times N_A = \dfrac{1}{8} N_A

Comparing the number of atoms, A, C, and E contain the same number of atoms.

Answer: A, C and E only
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