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JEE Main 20262 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
2 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Some Basic Concepts of Chemistry

JEE Main 2026 · 2 April · Evening Shift · Chemistry · Some Basic Concepts of Chemistry

The ratio of mass percentage (w/w) of C : H in a hydrocarbon is 12...

The ratio of mass percentage (w/w) of C : H in a hydrocarbon is 12:112 : 1. It has two carbon atoms. The weight (in g)ofCO2(g)of CO_2(g) formed when 3.383.38 g of this hydrocarbon is completely burnt in oxygen is : (Given : Molar mass in g mol−1^{-1} C : 12, H : 1, O : 16)

Options

  1. A5.685.68
  2. B11.4411.44
  3. C22.7422.74
  4. D17.0517.05

Correct answer

B. 11.4411.44

Step-by-step solution

Ratio of mass percentage of C : H = 12:112 : 1

Ratio of moles of C : H = 1212:11=1:1\dfrac{12}{12} : \dfrac{1}{1} = 1 : 1

The empirical formula is CHCH. Since the hydrocarbon has two carbon atoms, its molecular formula is C2H2C_2H_2.

Molar mass of C2H2=2×12+2×1=26C_2H_2 = 2 \times 12 + 2 \times 1 = 26 g mol−1^{-1}

Moles of C2H2C_2H_2 in 3.383.38 g = 3.3826=0.13\dfrac{3.38}{26} = 0.13 mol

The combustion reaction is:

C2H2+52O2→2CO2+H2OC_2H_2 + \dfrac{5}{2}O_2 \rightarrow 2CO_2 + H_2O

From the stoichiometry, 11 mole of C2H2C_2H_2 produces 22 moles of CO2CO_2.

Moles of CO2CO_2 produced = 2×0.13=0.262 \times 0.13 = 0.26 mol

Molar mass of CO2=12+2×16=44CO_2 = 12 + 2 \times 16 = 44 g mol−1^{-1}

Weight of CO2CO_2 formed = 0.26×44=11.440.26 \times 44 = 11.44 g

Answer: 11.4411.44
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