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JEE Main 202127 AugustEvening Shift
Exam
JEE Main
Year
2021
Date
27 August
Shift
Evening Shift
Subject
Chemistry
Chapter
States of Matter

JEE Main 2021 · 27 August · Evening Shift · Chemistry · States of Matter

Two flasks I and II shown below are connected by a valve of...

Two flasks I and II shown below are connected by a valve of negligible volume.

Two flasks I and II shown below are connected by a valve of negligible volume. When the valve is opened, the final

When the valve is opened, the final pressure of the system in bar is x×10−2x \times {10}^{- 2}. The value of xx is (Integer answer)
[Assume : Ideal gas; 11 bar =105Pa= {10}^{5}Pa : Molar mass of {N}_{2} = 28 . 0{mol}^{- 1}; R = 8 . 31J{mol}^{- 1}{K}^{- 1}]

Correct answer

0

Step-by-step solution

Applying ; (n−I+n− II ){\left(n - I + n -\text{ II }\right)}_{initial} =Thefinalnumberofmoles.</p><p>The final number of moles.</p><p>n - Iandn - IIarethenumberofmolesofgasineachcontainer.</p><p>are the number of moles of gas in each container.</p><p>⇒AssumingthesystemattainsafinaltemperatureofAssuming the system attains a final temperature ofT(suchthat(such that300 < T < 60)</p><p>)</p><p>⇒ \left\{∣\right) Heat lost by N2{N}_{2} of container (I)∣=∣( I ) | = | Heat gained by N2{N}_{2} of container II | }

⇒(n−I)Cm(300−T)=(n−II)Cm(T−60))</p><p>⇒ \left(n - I\right){C}_{m}\left(300 - T ) = \left(n - II\right){C}_{m} ( T - 60 )\right)</p><p>⇒ \left(\dfrac{2 . 8}{28}\right) ( 300 - T ) = \dfrac{0 . 2}{28} ( T - 60 )</p><p></p><p>⇒ 14 ( 300 - T ) = T - 60</p><p></p><p>⇒ \dfrac{( 14 \times 300 + 60 )}{15} = T</p><p></p><p>⇒ T = 284K(finaltemperature)</p><p>(final temperature)</p><p>⇒IfthefinalpressureIf the final pressure= P</p><p></p><p>⇒ {n}_{final} = \dfrac{3 . 0}{28}</p><p></p><p>⇒ \dfrac{P}{RT}\left({V}_{I} + {V}_{II}\right) = \dfrac{3 . 0gm}{28gm / mol}</p><p></p><p>P = \dfrac{3}{28}mol \times 8 . 31\dfrac{J}{mol - K} \times \dfrac{284K}{3 \times {10}^{- 3}{m}^{3}} \times {10}^{5}\dfrac{bar}{Pa}</p><p></p><p>⇒ 0 . 84287bar</p><p></p><p>⇒ 84 . 28 \times {10}^{- 2}bar</p><p></p><p>⇒ 84

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