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JEE Main 20262 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
2 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Structure of Atom

JEE Main 2026 · 2 April · Morning Shift · Chemistry · Structure of Atom

What is the energy (in J atom ^ -1 ) required for the following...

What is the energy (in J atom−1^{-1}) required for the following process?
Li2+(g)→Li3+(g)+e−Li^{2+}(g) \rightarrow Li^{3+}(g) + e^-
(Take the ionization energy for the H atom in the ground state as 2.18×10−182.18 \times 10^{-18} J atom−1^{-1})

Options

  1. A8.72×10−188.72 \times 10^{-18}
  2. B1.962×10−181.962 \times 10^{-18}
  3. C1.962×10−171.962 \times 10^{-17}
  4. D6.54×10−176.54 \times 10^{-17}

Correct answer

C. 1.962×10−171.962 \times 10^{-17}

Step-by-step solution

The given process Li2+(g)→Li3+(g)+e−Li^{2+}(g) \rightarrow Li^{3+}(g) + e^- represents the ionization of the hydrogen-like ion Li2+Li^{2+} from its ground state.

The ionization energy for a hydrogen-like species is given by the formula:
IE=IEH×Z2IE = IE_{H} \times Z^2

For Li2+Li^{2+}, the atomic number Z=3Z = 3.

Given the ionization energy of the hydrogen atom IEH=2.18×10−18IE_{H} = 2.18 \times 10^{-18} J atom−1^{-1}.

Substituting the values:
IE=2.18×10−18×(3)2IE = 2.18 \times 10^{-18} \times (3)^2

IE=2.18×10−18×9IE = 2.18 \times 10^{-18} \times 9

IE=19.62×10−18IE = 19.62 \times 10^{-18} J atom−1^{-1}

IE=1.962×10−17IE = 1.962 \times 10^{-17} J atom−1^{-1}

Answer: 1.962×10−171.962 \times 10^{-17}
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