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JEE Main 202228 JulyEvening Shift
Exam
JEE Main
Year
2022
Date
28 July
Shift
Evening Shift
Subject
Chemistry
Chapter
Structure of Atom

JEE Main 2022 · 28 July · Evening Shift · Chemistry · Structure of Atom

If the wavelength for an electron emitted from H - atom is 3 . 3 ×...

If the wavelength for an electron emitted from H−H - atom is 3.3×10−10m3 . 3 \times {10}^{- 10}m, then energy absorbed by the electron in its ground state compared to minimum energy required for its escape from the atom, is____times.
[Given : h=6.626×10−34Jsh = 6 . 626 \times {10}^{- 34}Js, Mass of electron =9.1×10−31= 9 . 1 \times {10}^{- 31}]

Correct answer

0

Step-by-step solution

De Broglie's equation for calculating the wave length(λ)( \lambda )~associated with the electron is given below

λ=hp=hmV\lambda = \dfrac{h}{p}= \dfrac{h}{mV}

Let Kinetic energy of the particle of mass 'm' is K

K=12mV22Km=m2V22Km=mVK = \dfrac{1}{2}{mV}^{2}2Km = m^{2}V^{2}\sqrt{2Km} = mV

λ=h2mK\lambda = \dfrac{h}{2mK}

hh=Planck's constant=6.62×10−27erg−sec6 . 62 \times {10}^{- 27}erg - sec

K=h22mλ2K = \dfrac{h2}{2{mλ}^{2}}

K=h22mλ2=43.9×10−682×9.1×10−31×10.89×10−20K = \dfrac{h2}{2{mλ}^{2}} = \dfrac{43 . 9 \times {10}^{- 68}}{2 \times 9 . 1 \times {10}^{- 31} \times 10 . 89 \times {10}^{- 20}}

K=2.215×10−18K = 2 . 215 \times {10}^{- 18}

Eabs=Ereq+KEabs=EnergyabsorbedEreq=EnergyrequiredK=KineticenergyEabsEreq=1+KEreq=1+2.215×10−1813.6×1.602×10−19=2.0166{E}_{abs} = {E}_{req} + K{E}_{abs} = Energyabsorbed{E}_{req =}EnergyrequiredK = Kineticenergy\dfrac{Eabs}{Ereq} = 1 + \dfrac{K}{Ereq} = 1 + \dfrac{2 . 215 \times {10}^{- 18}}{13 . 6 \times 1 . 602 \times {10}^{- 19}} = 2 . 0166

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