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JEE Main 202228 JulyEvening Shift
Exam
JEE Main
Year
2022
Date
28 July
Shift
Evening Shift
Subject
Chemistry
Chapter
Structure of Atom

JEE Main 2022 · 28 July · Evening Shift · Chemistry · Structure of Atom

Which of the following pair is not isoelectronic species? (Atomic...

Which of the following pair is not isoelectronic species?
(Atomic numbers Sm=62;Er=68;Yb=70;Lu=71;Eu=63;Tb=65;Tm=69Sm = 62; Er = 68; Yb = 70; Lu = 71; Eu = 63; Tb = 65; Tm = 69)

Options

  1. ASm2+{Sm}^{2 +} and Er3+{Er}^{3 +}
  2. BYb2+{Yb}^{2 +} and Lu3+{Lu}^{3 +}
  3. CEu2+{Eu}^{2 +} and Tb4+{Tb}^{4 +}
  4. DTb2+{Tb}^{2 +} and Tm4+{Tm}^{4 +}

Correct answer

D. Tb2+{Tb}^{2 +} and Tm4+{Tm}^{4 +}

Step-by-step solution

Isoelectronic species refers to two atoms, ions or molecules that have the same electronic structure and the same number of valence electrons term means "equal electric" or "equal charge". Isoelectronic chemical species typically display similar chemical properties.

\leftSm2+→electron=60Er3+→electron=65Tb2+→electron=63Tm4+→electron=65\begin{array}{ll}{Sm}^{2 +} \to electron = 60 \\ {Er}^{3 +} \to electron = 65 \\ {Tb}^{2 +} \to electron = 63 \\ {Tm}^{4 +} \to electron = 65\end{array}\right\} (not isoelectronic)

While Yb2+{Yb}^{2 +} and Lu3+{Lu}^{3 +} both will have 68 electrons. and Eu2+{Eu}^{2 +} and ${Tb}^{4 +} both will have 61 electrons.so, they are isoelectronic with each other.

Note: According to NTA only option D is given as answer but option A and D both will be the correct answer.

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