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JEE Main 202224 JuneMorning Shift
Exam
JEE Main
Year
2022
Date
24 June
Shift
Morning Shift
Subject
Chemistry
Chapter
Structure of Atom

JEE Main 2022 · 24 June · Morning Shift · Chemistry · Structure of Atom

Consider the following pairs of electrons (A) (a) n = 3, l = 1, m _...

Consider the following pairs of electrons

(A) (a) n=3,l=1,ml=1,ms=+12n = 3, l = 1, {m}_{l} = 1, {m}_{s} = + \dfrac{1}{2}
(b) n=3,l=2,ml=1,ms=+12n = 3, l = 2, {m}_{l} = 1, {m}_{s} = + \dfrac{1}{2}
(B) (a) n=3,l=2,ml=−2,ms=−12n = 3, l = 2, {m}_{l} = - 2, {m}_{s} = - \dfrac{1}{2}
(b) n=3,l=2,ml=−1,ms=−12n = 3, l = 2, {m}_{l} = - 1, {m}_{s} = - \dfrac{1}{2}
(C) (a) n=4,l=2,ml=2,ms=+12n = 4, l = 2, {m}_{l} = 2, {m}_{s} = + \dfrac{1}{2}
(b) n=3,l=2,ml=2,ms=+12n = 3, l = 2, {m}_{l} = 2, {m}_{s} = + \dfrac{1}{2}

The pairs of electrons present in degenerate orbitals is/are

Options

  1. AOnly (A)\left(A\right)
  2. BOnly (B)\left(B\right)
  3. COnly (C)\left(C\right)
  4. D(B)\left(B\right) and (C)\left(C\right) both

Correct answer

B. Only (B)\left(B\right)

Step-by-step solution

The orbitals which have same energy are called degenerate orbitals. Energy or an orbital depends on two quantum numbers, principle quantum number (n) and azimuthal quantum number (l).

The orbitals with similar values of n and ln \text{ and } l but with different value of mm will be degenerate orbitals.

Among the given set or orbital only option (B) fulfil this condition.

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