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JEE Main 20262 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
2 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Main 2026 · 2 April · Evening Shift · Chemistry · Thermodynamics (C)

Gas 'A' undergoes change from state 'X' to state 'Y'. In this...

Gas 'A' undergoes change from state 'X' to state 'Y'. In this process, the heat absorbed and work done by the gas is 1010 J and 1818 J respectively. Now gas is brought back to state 'X' by another process during which 66 J of heat is evolved. In the reverse process of 'Y' to 'X',

Options

  1. A1818 J of the work is done by the gas 'A'.
  2. B22 J of the work is done by the gas 'A'.
  3. C1212 J of the work is done on the gas 'A' by the surrounding.
  4. D1414 J of the work is done on the gas 'A' by the surrounding.

Correct answer

D. 1414 J of the work is done on the gas 'A' by the surrounding.

Step-by-step solution

Using the first law of thermodynamics, ΔU=q+w\Delta U = q + w.

For the process from state X to state Y:
Heat absorbed by the gas, qX→Y=+10q_{X \to Y} = +10 J
Work done by the gas, wX→Y=−18w_{X \to Y} = -18 J
Change in internal energy, ΔUX→Y=qX→Y+wX→Y=10−18=−8\Delta U_{X \to Y} = q_{X \to Y} + w_{X \to Y} = 10 - 18 = -8 J

For the reverse process from state Y to state X:
Change in internal energy, ΔUY→X=−ΔUX→Y=+8\Delta U_{Y \to X} = -\Delta U_{X \to Y} = +8 J
Heat evolved by the gas, qY→X=−6q_{Y \to X} = -6 J
Let the work done on the gas be wY→Xw_{Y \to X}.
ΔUY→X=qY→X+wY→X\Delta U_{Y \to X} = q_{Y \to X} + w_{Y \to X}
8=−6+wY→X8 = -6 + w_{Y \to X}
wY→X=+14w_{Y \to X} = +14 J

Since the work done is positive, 1414 J of work is done on the gas by the surrounding.

Answer: 1414 J of the work is done on the gas 'A' by the surrounding.
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