Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main20246 Apr 2024Morning ShiftChemistryThermodynamics (C)Actual

An ideal gas, ( C _ v = 5 2 R ), is expanded adiabatically against a constant pressure of 1 atm untill it doubles in volume. If the initial temperature and pressure is (298 ~K ) and (5 ~atm ), respectively then the final temperature is _______ ( K ) (nearest integer). [ ( C _ v ) is the molar heat capacity at constant volume]

Correct answer

0

Step-by-step solution

aligned & U = q + w ( q =0) & nC _ V T =- P _ ext ( V ₂- V ₁ ) & V ₂=2 ~V ₁ & nRT ₂ P ₂ = 2 nRT ₁ P ₁ & P ₁=5, ~T ₁=298 & P ₂= 5 ~T ₂ 2 298 & n 5 2 R ( T ₂- T ₁ )=-1 ( nRT ₂ P ₁ - nRT ₁ P ₁ ) aligned Put T ₁=298 and P ₂= 5 ~T ₂ 2 298 Solve and we get T₂=274.16 ~K T ₂ 274 ~K

Practice Thermodynamics (C) on Quantrex Academy →

More from Thermodynamics (C)

An ideal gas ( 0.5 mol), initially at 2 bar pressure, is compressed at a constant temperature of 600 K in two steps: first, against a constant external pressure of P bar ( 2 < P < 2026List-I contains various physical/chemical processes, and List-II contains combinations of changes in enthalpy ( H ) and entropy ( S ). Match each entry in List-I to the appropriate 2026Consider the reaction 2 H ₂ S (g) + 3 O ₂(g) 2 H ₂ O (l) + 2 SO ₂(g) The magnitude of enthalpy change for the reaction in kJ mol ⁻¹ is ________. (Nearest integer) Given: _fH^ ( H ₂ 2026Match List - I with List - II. Given V₁ and V₂ are initial and final volumes respectively. List - I (Isothermal process) List - II (Expression) A. Reversible expansion I. q = 0 B. 2026Arrange the following isothermal processes in order of the magnitude of the work ( p - V ) involved between states 1 and 2 . A. Expansion in single stage w_A B. Expansion in multi 2026Consider the reaction X Y at 300 K. If H^ and K are 28.40 kJ mol ⁻¹ and 1.8 10⁻⁷ at the same temperature, then the magnitude of S^ for the reaction in J K ⁻¹ mol ⁻¹ is _______. (Ne 2026Consider the following data for the reaction X₂(g) + Y₂(g) 2XY(g) at 600 K . The _r G^ (in kJ mol ⁻¹ ) for the reaction is : Compound _f H^ _ 600K (kJ mol ⁻¹ ) S^ _ 600K (J mol ⁻¹ 2026The correct order of molar heat capacities measured at 298 K and 1 bar is : 2026 Full Thermodynamics (C) list All JEE Main PYQs