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JEE Main 20236 AprilMorning Shift
Exam
JEE Main
Year
2023
Date
6 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Main 2023 · 6 April · Morning Shift · Chemistry · Thermodynamics (C)

The value of logK for the reaction A ⇌ B at 298K is _______ ....

The value of logKlogK for the reaction A⇌BA ⇌ B at 298K298K is _______ . (Nearest integer)

Given: \DeltaH°=−54.07kJmol−1\DeltaH ° = - 54 . 07kJ{mol}^{- 1}

\DeltaS°=10JK−1mol−1\DeltaS ° = 10{JK}^{- 1}{mol}^{- 1}

(Taken 2.303×8.314×298=57052 . 303 \times 8 . 314 \times 298 = 5705 )

Correct answer

0

Step-by-step solution

We can use the relationship between the equilibrium constant (KK) and the standard Gibbs free energy change (ΔG°\Delta G °) to calculate the value of logKlogK at 298K298K

Given,

∆Ho=–54.07kJmol–1∆So=10JK–1mol–1∆ {H}^{o} = – 54 . 07kJ{mol}^{– 1} ∆ {S}^{o} = 10{JK}^{– 1}{mol}^{– 1}

We know,

∆G°=∆H°−T∆S°∆ G ° = ∆ H ° - T ∆ S °

=−54.07−298(10)1000= - 54 . 07 - \dfrac{298 ( 10 )}{1000}

=−57.05kJ/mole= - 57 . 05kJ / mole

∆G°=−2.303RTlogKeq∆ G ° = - 2 . 303RT{logK}_{\text{eq}}

−57.05×1000=−2.303×8.314×298logKeq- 57 . 05 \times 1000 = - 2 . 303 \times 8 . 314 \times 298{logK}_{\text{eq}}

−57.05×1000=−5705log⁡eq- 57 . 05 \times 1000 = - 5705\log_{eq}

10=logKeq10 = {logK}_{\text{eq}}

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