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JEE Main 20231 FebruaryEvening Shift
Exam
JEE Main
Year
2023
Date
1 February
Shift
Evening Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Main 2023 · 1 February · Evening Shift · Chemistry · Thermodynamics (C)

0 . 3g of ethane undergoes combustion at 27 ° C in a bomb...

0.3g0 . 3g of ethane undergoes combustion at 27°C27 ° C in a bomb calorimeter. The temperature of calorimeter system (including the water) is found to rise by 0.5°C0 . 5 ° C. The heat evolved during combustion of ethane at constant pressure is kJmol−1{kJmol}^{- 1}.
(Nearest integer)

[Given : The heat capacity of the calorimeter system is 20kJK−1,R=8.3JK−1mol−120kJ{K}^{- 1}, R = 8 . 3{JK}^{- 1}{mol}^{- 1}.
Assume ideal gas behaviour.

Assume ideal gas behaviour.

Atomic mass of CC and HH are 1212 and 1gmol−11g{mol}^{- 1} respectively]

Correct answer

0

Step-by-step solution

The bomb calorimeter is an instrument used to measure the heat of reaction at a fixed volume and the measured heat which is called the change of internal energy.
By combustion of 11 mole

C2H6(ΔU)=−Heatcapacity×∆Tmass×Molarmass=−20×0.50.3×30=−1000kJ{C}_{2}{H}_{6} ( \Delta U ) = - \dfrac{Heatcapacity \times ∆ T}{mass} \times Molarmass = - \dfrac{20 \times 0 . 5}{0 . 3} \times 30 = - 1000kJ

C2H6(g)+7/2O2(g)→2CO2(g)+3H2O(l){C}_{2}{H}_{6} ( g ) + 7 / 2{O}_{2} ( g ) \to 2{CO}_{2} ( g ) + 3{H}_{2}O ( l )

\Deltang=2−(2+7/2)=−(7/2)\Deltang = 2 - ( 2 + 7 / 2 ) = - ( 7 / 2 )

ΔH=ΔU+ΔnRT\Delta H = \Delta U + \Delta nRT

=−1000−7/2×8.3×300kJ= - 1000 - 7 / 2 \times 8 . 3 \times 300kJ

=−1000−6.225= - 1000 - 6 . 225

=−1006kJ= - 1006kJ

So heat released =1006kJmol−1= 1006kJ{mol}^{- 1}

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