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JEE Main 202324 JanuaryMorning Shift
Exam
JEE Main
Year
2023
Date
24 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Main 2023 · 24 January · Morning Shift · Chemistry · Thermodynamics (C)

For independent process at 300K . Process / kJmol ^ - 1 / JK ^ - 1...

For independent process at 300K300K.

Process \DeltaH/kJmol−1\DeltaH / {kJmol}^{- 1} \DeltaS/JK−1\DeltaS / {JK}^{- 1}
AA −25- 25 −80- 80
BB −22- 22 4040
CC 2525 −50- 50
DD 2222 2020

The number of non-spontaneous process from the following is _____ .

Correct answer

0

Step-by-step solution

The relation between change in Gibbs free energy, change in enthalpy and change in entropy can be written as follows,

ΔG=ΔH−TΔS\Delta G = \Delta H - T \Delta S

If ∆G∆ G is +ve+ ve , then the process is said to be non-spontaneous and if ∆G∆ G is −ve- ve then the process is said to be spontaneous.

A:ΔG(Jmol−1)=−25×103+80×300:−veA: \Delta G\left({Jmol}^{- 1}\right) = - 25 \times {10}^{3} + 80 \times 300: - ve

B:ΔG(Jmol−1)=−22×103−40×300:−veB: \Delta G\left({Jmol}^{- 1}\right) = - 22 \times {10}^{3} - 40 \times 300: - ve

C:ΔG(Jmol−1)=25×103+300×50;+veC: \Delta G\left({Jmol}^{- 1}\right) = 25 \times {10}^{3} + 300 \times 50; + ve

D:ΔG(Jmol−1)=22×103−20×300:+veD: \Delta G\left({Jmol}^{- 1}\right) = 22 \times {10}^{3} - 20 \times 300: + ve

Processes CC and DD are non-spontaneous.

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