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JEE Main 202226 JulyEvening Shift
Exam
JEE Main
Year
2022
Date
26 July
Shift
Evening Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Main 2022 · 26 July · Evening Shift · Chemistry · Thermodynamics (C)

For the reaction H _ 2 F _ 2 (g) → H _ 2 (g) + F _ 2 (g) Δ U = - 59...

For the reaction H2F2(g){H}_{2}{F}_{2}\left(g\right) \to {H}_{2}\left(g\right)+F2(g)+ {F}_{2}\left(g\right)

ΔU=−59.6kJmol−1\Delta U = - 59 . 6kJ{mol}^{- 1} at 27°C27 ° C

The enthalpy change for the above reaction is \left(-\right)____{kJmol}^{- 1}(nearestinteger)</p><p>(Given:(nearest integer)</p><p>(Given :R = 8 . 314{JK}^{- 1}{mol}^{- 1}$) .

Correct answer

0

Step-by-step solution

For the reaction H2F2(g)→H2(g)+F2(g){H}_{2}{F}_{2}\left(g\right) \to {H}_{2}\left(g\right) + {F}_{2}\left(g\right)

ΔH=ΔU+(Δng)RT\Delta H = \Delta U + \left({\Delta n}_{g}\right)RT

Given ΔU=−59.6kJmol−1\Delta U = - 59 . 6kJ{mol}^{- 1}

Δng=2−1{\Delta n}_{g} = 2 - 1

=−59.6+1×8.3141000×300= - 59 . 6 + 1 \times \dfrac{8 . 314}{1000} \times 300

=−57.11kJmol−1= - 57 . 11kJ{mol}^{- 1}

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