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JEE Main 202224 JuneMorning Shift
Exam
JEE Main
Year
2022
Date
24 June
Shift
Morning Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Main 2022 · 24 June · Morning Shift · Chemistry · Thermodynamics (C)

2 O _ 3 (g) ⇌ 3 O _ 2 (g) At 300K , ozone is fifty percent...

2{O}_{3}(g)\left(g\right) ⇌ 3{O}_{2}\left(g\right)</p><p>At</p><p>At300K,ozoneisfiftypercentdissociated.Thestandardfreeenergychangeatthistemperatureand, ozone is fifty percent dissociated. The standard free energy change at this temperature and1atmpressureis(−)pressure is \left(-\right) . . . . . . J{mol}^{- 1}.(Nearestinteger)</p><p>[Given:. (Nearest integer)</p><p>[Given:\ln 1 . 35 = 0 . 3 and R = 8 . 3J{K}^{- 1}{mol}^{- 1}]</p>]</p>

Correct answer

0

Step-by-step solution

2{O}_{3}\left(g\right) ⇌ 3{O}_{2}\left(g\right)</p><p>Initially</p><p>Initially1molemole0</p><p>(1−0.5)</p><p>\left(1 - 0 . 5\right)\dfrac{3}{2} \times 0 . 5</p><p></p><p>0 . 5molemole\dfrac{1 . 5}{2} = 0 . 75mole</p><p>mole</p><p>{K}_{p} = \dfrac{{\left({P}_{{O}_{2}}\right)}^{3}}{{\left({P}_{{O}_{3}}\right)}^{2}} = \dfrac{{\left(\dfrac{0 . 75}{1 . 25}\right)}^{3}}{{\left(\dfrac{0 . 5}{1 . 25}\right)}^{2}} = \dfrac{{\left(\dfrac{3}{5}\right)}^{3}}{{\left(\dfrac{2}{5}\right)}^{2}}</p><p></p><p>= \dfrac{{\left(0 . 6\right)}^{3}}{{\left(0 . 4\right)}^{2}} = \dfrac{\left(0 . 216\right)}{\left(0 . 16\right)} = 1 . 35</p><p></p><p>\Delta G ° = - {RTlnK}_{p}</p><p></p><p>= - 8 . 3 \times 300\ln 1 . 35</p><p></p><p>= - 8 . 3 \times 300 \times 0 . 3</p><p></p><p>= - 747J / mole

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