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JEE Main202127 Jul 2021Morning ShiftChemistryThermodynamics (C)Actual

For water at 100 ° C and 1 bar, Δ v a p H - Δ v a p U = ¯ × 10 2 J mol - 1 (Round off to the Nearest Integer) [Use : R = 8 . 31 J mol - 1 K - 1 [Assume volume of H 2 O ( l ) is much smaller than volume of H 2 O ( g ) . Assume H 2 O ( g ) treated as an ideal gas]

Correct answer

0

Step-by-step solution

H 2 O ( ℓ ) ⇌ H 2 O ( v ) ΔH = ΔU + Δn g RT for 1 mole waters ; Δn g = 1 ∴   Δn g RT = 1   mol × 8 . 31   J / mol - k × 373   K = 3099 . 63   J ≅ 31 × 10 2   J

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