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JEE Main 20206 SeptemberMorning Shift
Exam
JEE Main
Year
2020
Date
6 September
Shift
Morning Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Main 2020 · 6 September · Morning Shift · Chemistry · Thermodynamics (C)

The variation of equilibrium constant with temperature is given...

The variation of equilibrium constant with temperature is given below :

{TemperatureEquilibriumConstantT1=25°CK1=10T2=100°CK2=100\begin{cases}Temperature & EquilibriumConstant \\ {T}_{1} = 25 ° C & {K}_{1} = 10 \\ {T}_{2} = 100 ° C & {K}_{2} = 100\end{cases}

The values of ΔH°,ΔG°\Delta H ° , \Delta G ° at T1{T}_{1} and \DeltaG°\DeltaG ° at T2{T}_{2} (in kJmol−1kJ{mol}^{- 1} ) respectively, are close to [use R=8.314JK−1mol−1R = 8 . 314{JK}^{- 1}{mol}^{- 1}]

Options

  1. A28.4,−7.14and−5.7128 . 4, - 7 . 14\text{and} - 5 . 71
  2. B0.64,−7.14and−5.710 . 64, - 7 . 14\text{and} - 5 . 71
  3. C28.4,−5.71and−14.2928 . 4, - 5 . 71\text{and} - 14 . 29
  4. D0.64,−5.71and−14.290 . 64, - 5 . 71and - 14 . 29

Correct answer

A. 28.4,−7.14and−5.7128 . 4, - 7 . 14\text{and} - 5 . 71

Step-by-step solution

T1=323KT2=373K{T}_{1} = 323K{T}_{2} = 373K
k1=10k2=100{k}_{1} = 10{k}_{2} = 100
log⁡(k2k1)=\DeltaH2.303R[1T1−1T2]\log \left(\dfrac{{k}_{2}}{{k}_{1}}\right) = \dfrac{\DeltaH}{2 . 303R}\left[\dfrac{1}{{T}_{1}} - \dfrac{1}{{T}_{2}}\right]

log⁡(10010)=\DeltaH2.303×8.314[1298−1373]\log \left(\dfrac{100}{10}\right) = \dfrac{\DeltaH}{2 . 303 \times 8 . 314}\left[\dfrac{1}{298} - \dfrac{1}{373}\right]

log⁡10=\DeltaH2.303×8.314[75298×373]\log 10 = \dfrac{\DeltaH}{2 . 303 \times 8 . 314}\left[\dfrac{75}{298 \times 373}\right]

\DeltaH=2.303×8.314×298×37375=28.4KJ\DeltaH = \dfrac{2 . 303 \times 8 . 314 \times 298 \times 373}{75} = 28 . 4KJ

At T1=25°C=298K,K1=10{T}_{1} = 25 ° C = 298K, {K}_{1} = 10

\DeltaG=−2.303RT1logk1\DeltaG = - 2 . 303{RT}_{1}{\text{logk}}_{1}

=−2.303×8.314×298×log⁡(10)= - 2 . 303 \times 8 . 314 \times 298 \times \log ( 10 )

=−2.303×8.314×298×1= - 2 . 303 \times 8 . 314 \times 298 \times 1

=−5.7KJ= - 5 . 7KJ

At T2=100°C=373KK2=100{T}_{2} = 100 ° C = 373K{K}_{2} = 100

\DeltaG=−2.303RT2logK2\DeltaG = - 2 . 303{RT}_{2}{logK}_{2}

=−2.303×8.314×373×log⁡(10)2= - 2 . 303 \times 8 . 314 \times 373 \times \log ( 10{)}^{2}

=−2.303×2×8.314×373×1= - 2 . 303 \times 2 \times 8 . 314 \times 373 \times 1

=−14283.7J= - 14283 . 7J

=−14.29KJ= - 14 . 29KJ

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