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JEE Main20198 Apr 2019Evening ShiftChemistryThermodynamics (C)Actual

5 moles of an ideal gas at 100 K are allowed to undergo reversible compression till its temperature becomes 200 K . If C V = 28 J K - 1 , calculate ∆ U and ∆ p V for the process. ( R = 8.0 J K - 1 m o l - 1 )

Options

  1. A∆ U = 14 J ; ∆ p V = 0.8 J
  2. B∆ U = 14   kJ ;   ∆ p V = 18   kJ
  3. C∆ U = 14   kJ ;   ∆ p V = 4   kJ
  4. D∆ U = 2.8   kJ ;   ∆ p V = 0.8   kJ

Correct answer

C. ∆ U = 14   kJ ;   ∆ p V = 4   kJ

Step-by-step solution

Δ U = n C V Δ T = 5 × 28 × 100 = 14000   J = 14   kJ Δ ( P V ) = n R Δ T = 5 × 8 × 100 = 4000   J = 4   k J

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