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JEE Main201911 Jan 2019Morning ShiftChemistryThermodynamics (C)Actual

Two blocks of the same metal having same mass and at temperature T ₁, and T ₂ , respectively, are brought in contact with each other and allowed to attain thermal equilibrium at constant pressure. The change in entropy, S , for this process is :

Options

  1. AC _ P [ ( T ₁+ T ₂ )² 4 ~T ₁ ~T ₂ ]
  2. B2 C_ p [ (T₁+T₂ )^ 1 2 T₁ T₂ ]
  3. C2 C _ P ( T ₁+ T ₂ 4 ~T ₁ ~T ₂ )
  4. D2 C _ P [ T ₁+ T ₂ 2 ~T ₁ ~T ₂ ]

Correct answer

A. C _ P [ ( T ₁+ T ₂ )² 4 ~T ₁ ~T ₂ ]

Step-by-step solution

Final temperature = T ₁+ T ₂ 2 , let T ₂> T dS = dq T = C _ p dT T S = C _ p ( T _ f T _ i ) S _ Total = C _ p ( T ₁+ T ₂ 2 ~T ₁ )+ C _ p ( T ₁+ T ₂ 2 ~T ₂ ) = C _ p [ ( T ₁+ T ₂ )² 4 ~T ₁ ~T ₂ ]

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