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JEE Main2014ChemistryThermodynamics (C)Actual

The standard enthalpy of formation of NH 3 is - 46 . 0 kJ / mol . If bond enthalpy of H 2 is - 436 kJ / mol and that of N 2 is - 712 kJ / mol , the average bond enthalpy of N - H bond in NH 3 is :

Options

  1. A-   964   kJ / mol
  2. B-   1102   kJ / mol
  3. C+   1056   kJ / mol
  4. D+   352   kJ / mol

Correct answer

D. +   352   kJ / mol

Step-by-step solution

For The Reaction 1 2 N 2 g + 3 2 H 2 g → NH 3 g ; Δ H f ∘ = - 4 6 KJ mol - 1 Δ H f ∘ = - 4 6 = ∑ B.E - ∑ B.E Reactants Product ∑ B.E = ∑ B.E + 4 6 Product Reactants = 1 2 7 1 2 + 3 2 4 3 6 + 4 6 = 356 + 654 + 46 = 1056 Averge B.E for N-H Bond = 1 0 5 6 3 = 3 5 2 KJ mol - 1

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