AIIMS2016ChemistryChemical Bonding and Molecular Structure
Assertion : bond angle is less than the normal tetrahedral bond angle. Reason : Lone pair-lone pair repulsion decreases bond angle.
Options
- AIf both assertion and reason are true and reason is the correct explanation of assertion.
- BIf both assertion and reason are true but reason is not the correct explanation of assertion.
- CIf assertion is true but reason is false.
- DIf both assertion and reason are false.
Correct answer
A. If both assertion and reason are true and reason is the correct explanation of assertion.
Step-by-step solution
The bond angle in alcohols is slightly less than the tetrahedral angle 109^ 28^ due to repulsion between the unshared electron pairs of oxygen.