AIIMS 2013
- Exam
- AIIMS
- Year
- 2013
- Subject
- Chemistry
- Chapter
- Chemical Bonding and Molecular Structure
AIIMS 2013 · Chemistry · Chemical Bonding and Molecular Structure
Assertion : Bond lengths of P-Cl bonds in gaseous PCl_5 and solid...
Assertion : Bond lengths of bonds in gaseous and solid are not equal.
Reason : Because in solid state two molecules are associated.
Options
- AIf both assertion and reason are true and reason is the correct explanation of assertion.
- BIf both assertion and reason are true but reason is not the correct explanation of assertion.
- CIf assertion is true but reason is false.
- DIf both assertion and reason are false.
Correct answer
A. If both assertion and reason are true and reason is the correct explanation of assertion.
Step-by-step solution
As in solid state, exists as an ionic solid \left[\mathrm{PCl}_4\right]^{+}in which the cation, \left[\mathrm{PCl}_4\right]^{+} is tetrahedral and the anion, is octahedral. in gaseous state has trigonal bipyramidal structure in which three equatorial bonds are equivalent, while the two axial bonds are longer than equatorial bonds due to more bond pair repulsion.