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AIIMS 2013
Exam
AIIMS
Year
2013
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

AIIMS 2013 · Chemistry · Chemical Bonding and Molecular Structure

Assertion : Bond lengths of P-Cl bonds in gaseous PCl_5 and solid...

Assertion : Bond lengths of P−Cl\mathrm{P}-\mathrm{Cl} bonds in gaseous PCl5\mathrm{PCl}_5 and solid PCl5\mathrm{PCl}_5 are not equal. Reason : Because in solid state two PCl5\mathrm{PCl}_5 molecules are associated.

Options

  1. AIf both assertion and reason are true and reason is the correct explanation of assertion.
  2. BIf both assertion and reason are true but reason is not the correct explanation of assertion.
  3. CIf assertion is true but reason is false.
  4. DIf both assertion and reason are false.

Correct answer

A. If both assertion and reason are true and reason is the correct explanation of assertion.

Step-by-step solution

As in solid state, PCl5\mathrm{PCl}_5 exists as an ionic solid \left[\mathrm{PCl}_4\right]^{+}[PCl6]−\left[\mathrm{PCl}_6\right]^{-}in which the cation, \left[\mathrm{PCl}_4\right]^{+} is tetrahedral and the anion, [PCl6]−\left[\mathrm{PCl}_6\right]^{-}is octahedral. PCl5\mathrm{PCl}_5 in gaseous state has trigonal bipyramidal structure in which three equatorial bonds are equivalent, while the two axial bonds are longer than equatorial bonds due to more bond pair repulsion.
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