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AIIMS 2012
Exam
AIIMS
Year
2012
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

AIIMS 2012 · Chemistry · Chemical Bonding and Molecular Structure

Which is not stable under ambient condition?

Which is not stable under ambient condition?

Options

  1. ATiO2,Ti+4\mathrm{TiO}_2, \mathrm{Ti}^{+4}
  2. BVO,V+4\mathrm{VO}, \mathrm{V}^{+4}
  3. CVO2, V+5\mathrm{VO}_2, \mathrm{~V}^{+5}
  4. DCu2O,Cu+2\mathrm{Cu}_2 \mathrm{O}, \mathrm{Cu}^{+2}

Correct answer

D. Cu2O,Cu+2\mathrm{Cu}_2 \mathrm{O}, \mathrm{Cu}^{+2}

Step-by-step solution

Copper (I) compounds are unstable in aqueous solution and undergo disproportio-nation. 2Cu+→Cu2++Cu2 \mathrm{Cu}^{+} \rightarrow \mathrm{Cu}^{2+}+\mathrm{Cu} The greater stability of Cu2+(aq.)\mathrm{Cu}^{2+}{ }_{(a q .)} than Cu+(aq.)\mathrm{Cu}^{+}{ }_{(a q .)} is due to much more −veΔhydH-v e \Delta_{h y d} H of Cu2+(aq.)\mathrm{Cu}^{2+}{ }_{(a q .)} than Cu(aq.)+\mathrm{Cu}_{(a q .)}^{+}, which compensates for the second ionisation enthalpy of Cu\mathrm{Cu}.
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