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AIIMS 2007
Exam
AIIMS
Year
2007
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

AIIMS 2007 · Chemistry · Chemical Bonding and Molecular Structure

The order of bond length is

The order of bond length isThe order of bond length is

Options

  1. A(\mathrm{O}_2 < \mathrm{O}_3 < \mathrm{O}_2{ }^{2-})
  2. B(\mathrm{O}_2 < \mathrm{O}_2{ }^{2-} < \mathrm{O}_3)
  3. C(\mathrm{O}_2{ }^{2-} < \mathrm{O}_3 < \mathrm{O}_2)
  4. D(\mathrm{O}_2=\mathrm{O}_2{ }^{2-} > \mathrm{O}_3).

Correct answer

A. (\mathrm{O}_2 < \mathrm{O}_3 < \mathrm{O}_2{ }^{2-})

Step-by-step solution

Ozone molecule is V-shaped with (\mathrm{O}-\mathrm{O}) bond length 1.278A˚1.278 Å. The order of bond length is
The bond length is intermediate between that for a single bond (\left(1.48 Å\right.) as in (\left.\mathrm{H}_2 \mathrm{O}_2\right)) and for a double bond (1.21 A˚Å as in (\mathrm{O}_2)).
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