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AIIMS 2003
Exam
AIIMS
Year
2003
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

AIIMS 2003 · Chemistry · Chemical Bonding and Molecular Structure

Which of the following are arranged in the decreasing order of...

Which of the following are arranged in the decreasing order of dipole moment?

Options

  1. ACH3Cl,CH3Br,CH3 F\mathrm{CH}_3 \mathrm{Cl}, \mathrm{CH}_3 \mathrm{Br}, \mathrm{CH}_3 \mathrm{~F}
  2. BCH3Cl,CH3 F,CH3Br\mathrm{CH}_3 \mathrm{Cl}, \mathrm{CH}_3 \mathrm{~F}, \mathrm{CH}_3 \mathrm{Br}
  3. CCH3Br,CH3Cl,CH3 F\mathrm{CH}_3 \mathrm{Br}, \mathrm{CH}_3 \mathrm{Cl}, \mathrm{CH}_3 \mathrm{~F}
  4. DCH3Br,CH3 F,CH3Cl\mathrm{CH}_3 \mathrm{Br}, \mathrm{CH}_3 \mathrm{~F}, \mathrm{CH}_3 \mathrm{Cl}

Correct answer

B. CH3Cl,CH3 F,CH3Br\mathrm{CH}_3 \mathrm{Cl}, \mathrm{CH}_3 \mathrm{~F}, \mathrm{CH}_3 \mathrm{Br}

Step-by-step solution

The values of dipole moments of methyl halides: \begin{aligned} \mathrm{CH}_{3} \mathrm{ F}-1.51 \mathrm{D}; \mathrm{CH}_{3} \mathrm{Cl}-1.56 \mathrm{D}; \\ \mathrm{CH}_{3} \mathrm{Br}-1.4 \mathrm{D}; \mathrm{CH}_{3} \mathrm{I}-1.29 \mathrm{D}\\ & \therefore \quad \mathrm{CH}_{3} \mathrm{Cl}> \mathrm{CH} }_{3} \mathrm{ F}>\mathrm{CH}_{3} \mathrm{Br} > \mathrm{CH} }_{3} \mathrm{I}. \end{aligned}
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