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JIPMER 2009
Exam
JIPMER
Year
2009
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JIPMER 2009 · Chemistry · Chemical Bonding and Molecular Structure

H-O-H bond angle in H_2 O is 104.5^ and not 109^ 28^ because of

H−O−H\mathrm{H}-\mathrm{O}-\mathrm{H} bond angle in H2O\mathrm{H}_2 \mathrm{O} is 104.5∘104.5^{\circ} and not 109∘28′109^{\circ} 28^{\prime} because of

Options

  1. Alone pair-lone pair repulsion
  2. Blone pair-bond pair repulsion
  3. Cbond pair-bond pair repulsion
  4. Dhigh electronegativity of oxygen

Correct answer

A. lone pair-lone pair repulsion

Step-by-step solution

The hybridisation of oxygen in water molecule is sp3s p^3. So, water molecule must be tetrahedral and have bond angle 109∘28′109^{\circ} 28^{\prime}. But due to the presence of two lone pair of electrons on oxygen atom (repulsion between lone pair-lone pair) the bond angle decreases about 104.5∘104.5^{\circ} and the geometry becomes distorted tertrahedral or V-shaped.
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