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JIPMER 2018
Exam
JIPMER
Year
2018
Subject
Chemistry
Chapter
Chemical Equilibrium

JIPMER 2018 · Chemistry · Chemical Equilibrium

A chemical reaction was carried out at 300 K and 280 K . The rate...

A chemical reaction was carried out at 300 K and 280 K . The rate constant were found to be k1\mathrm{k}_1 and k2\mathrm{k}_2 respectively, then

Options

  1. Ak2=4k1k_2=4 k_1
  2. Bk2=0.25k1k_2=0.25 k_1
  3. Ck2=2k1k_2=2 \mathrm{k}_1
  4. Dk2=0.5k1k_2=0.5 \mathrm{k}_1

Correct answer

B. k2=0.25k1k_2=0.25 k_1

Step-by-step solution

For every 10∘C10^{\circ} \mathrm{C} rise, rate constant gets doubled. Hence, for every 20∘C20^{\circ} \mathrm{C} rise, rate constant will be 4 times. Therefore, according to the given statement, Temperature 280 K300 K\quad 280 \mathrm{~K} \quad 300 \mathrm{~K} Rate constant k2k1\quad \mathrm{k}_2 \quad \mathrm{k}_1\left(4 \mathrm{k}_2\right)Thus,Thus,\quad \mathrm{k}_1=4 \mathrm{k}_2 \Rightarrow \mathrm{k}_2=0.25 \mathrm{k}_1
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