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JIPMER 2017
Exam
JIPMER
Year
2017
Subject
Chemistry
Chapter
General Organic Chemistry

JIPMER 2017 · Chemistry · General Organic Chemistry

The most stable carbonium ion among the following is

The most stable carbonium ion among the following is

Options

  1. AC6H5−CH2C+H2\mathrm{C}_6 \mathrm{H}_5-\mathrm{CH}_2 \stackrel{+}{\mathrm{C}} \mathrm{H}_2
  2. BCH3C+H2\mathrm{CH}_3 \stackrel{+}{\mathrm{C}} \mathrm{H}_2
  3. CC6H5−C+−C6H5\mathrm{C}_6 \mathrm{H}_5-\stackrel{+}{\mathrm{C}}-\mathrm{C}_6 \mathrm{H}_5
  4. DC6H5C+H2\mathrm{C}_6 \mathrm{H}_5 \stackrel{+}{\mathrm{C}} \mathrm{H}_2

Correct answer

C. C6H5−C+−C6H5\mathrm{C}_6 \mathrm{H}_5-\stackrel{+}{\mathrm{C}}-\mathrm{C}_6 \mathrm{H}_5

Step-by-step solution

Due to more possibility for delocalisation in C6H5−C+−C6H5\mathrm{C}_6 \mathrm{H}_5-\stackrel{+}{\mathrm{C}}-\mathrm{C}_6 \mathrm{H}_5 (of π\pi-electrons), C6H5−C+−C6H5\mathrm{C}_6 \mathrm{H}_5-\stackrel{+}{\mathrm{C}}-\mathrm{C}_6 \mathrm{H}_5 is the most stable ion.
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