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JIPMER 2007
Exam
JIPMER
Year
2007
Subject
Chemistry
Chapter
General Organic Chemistry

JIPMER 2007 · Chemistry · General Organic Chemistry

Which one of the following is expected to exhibit optical...

Which one of the following is expected to exhibit optical isomerism? (en = ethylenediamine ))Which one of the following is expected to exhibit optical isomerism? (en = ethylenediamine )Which one of the following is expected to exhibit optical isomerism? (en = ethylenediamine )

Options

  1. Acis−[Pt(NH3)2Cl2]c i s-\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right]
  2. Btrans- [Co(en)2Cl2]\left[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2\right]
  3. Ctrans⁡−[Pt(NH3)2Cl2]\operatorname{trans}-\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right]
  4. Dcis⁡−[(Co(en)2Cl2]\operatorname{cis}-\left[\left(\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2\right]\right.

Correct answer

B. trans- [Co(en)2Cl2]\left[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2\right]

Step-by-step solution

Cis (-\left[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2\right]^{+}) is able to show the phenomenon of optical isomerism because it can form a superimposable mirror image. Which one of the following is expected to exhibit optical isomerism? (en = ethylenediamine ) It gives super imposable structure but trans-form is optically inactive. Which one of the following is expected to exhibit optical isomerism? (en = ethylenediamine )
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