JIPMER2005ChemistryGeneral Organic Chemistry
Which carbocation is most stable?
Options
- ACH ₃ CH ₂⁺
- BCH ₃⁺
- CC ₆ H ₅ CH ₂⁺
- DCH ₃ CH ₂ CH ₂⁺
Correct answer
C. C ₆ H ₅ CH ₂⁺
Step-by-step solution
A phenyl group, in which there is a flow of electron due to resonance of the benzene ring, generally causes -I effect, but truely speaking it can act as both electron donating as well as electron withdrawing groups, depending upon the nature of group with which it is attached. In C ₆ H ₅ CH ₂⁺ , phenyl group is attached to electron deficient group, hence it will donate electron due to resonance in benzene ring and thus stabilise the cation.