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JIPMER 2007
Exam
JIPMER
Year
2007
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

JIPMER 2007 · Chemistry · p Block Elements (Group 13 & 14)

Which of the following is the electron deficient molecule?

Which of the following is the electron deficient molecule?Which of the following is the electron deficient molecule?

Options

  1. AB2H6\mathrm{B}_2 \mathrm{H}_6
  2. BC2H6\mathrm{C}_2 \mathrm{H}_6
  3. CPH3\mathrm{PH}_3
  4. DSiH4\mathrm{SiH}_4

Correct answer

A. B2H6\mathrm{B}_2 \mathrm{H}_6

Step-by-step solution

B2H6\mathrm{B}_2 \mathrm{H}_6 is electron deficient molecule because boron atom has three half filled orbitals in excited state. The structure of B2H6\mathrm{B}_2 \mathrm{H}_6 is represented as follows: Which of the following is the electron deficient molecule? In it two electrons of a B−H\mathrm{B}-\mathrm{H} bond are involved in formation of three centre bond, these bonds are represented as dotted lines.
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