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NEET 2007
Exam
NEET
Year
2007
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

NEET 2007 · Chemistry · p Block Elements (Group 13 & 14)

Which of the following oxidation states are the most...

Which of the following oxidation states are the most characteristics for lead and tin respectively?

Options

  1. A+2,+4+2,+4
  2. B+4,+4+4,+4
  3. C+2,+2+2,+2
  4. D+4,+2+4,+2

Correct answer

A. +2,+4+2,+4

Step-by-step solution

The group IV elements show tetravalency due to shifting of one electrons of nsn s to the vacant npn p orbital. These four orbitals give rise to four sp3s p^3 hybrid orbitals. However, Ge,Sn\mathrm{Ge}, \mathrm{Sn} and Pb\mathrm{Pb}, have a tendency to form divalent as well as tetravalent ions. As the inert pair effect increases from Ge\mathrm{Ge} to Pb\mathrm{Pb}, the stability of tetravalent ion decreases and that of divalent ion increases. Thus, Pb++\mathrm{Pb}^{++}is more stable than Pb4+\mathrm{Pb}^{4+} and Sn4+\mathrm{Sn}^{4+} ions is more stable than Sn2+\mathrm{Sn}^{2+}.
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