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JIPMER 2016
Exam
JIPMER
Year
2016
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JIPMER 2016 · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Consider the reaction, H_2+X_2 2 H X , where X is halogen. The...

Consider the reaction, H2+X2⟶2HX\mathrm{H}_2+X_2 \longrightarrow 2 \mathrm{H} X, where XX is halogen. The reactivity of halogens decrease in the order of

Options

  1. ACl2>F2>Br2>\mathrm{Cl}_2\gt\mathrm{F}_2\gt\mathrm{Br}_2\gt\mathrm{I}2_2
  2. BI2>Br2>F2>Cl2\mathrm{I}_2\gt\mathrm{Br}_2\gt\mathrm{F}_2\gt\mathrm{Cl}_2
  3. CF2>Cl2>Br2>\mathrm{F}_2\gt\mathrm{Cl}_2\gt\mathrm{Br}_2\gt\mathrm{I}2_2
  4. DI2>Br2>Cl2>F2\mathrm{I}_2\gt\mathrm{Br}_2\gt\mathrm{Cl}_2\gt\mathrm{F}_2

Correct answer

C. F2>Cl2>Br2>\mathrm{F}_2\gt\mathrm{Cl}_2\gt\mathrm{Br}_2\gt\mathrm{I}2_2

Step-by-step solution

H−H+X−X⟶2HX\mathrm{H}-\mathrm{H}+\mathrm{X}-\mathrm{X} \longrightarrow 2 \mathrm{HX}, where X=X= halogen. The correct decreasing order of reactivity of halogen molecule towards H2\mathrm{H}_2 is F2>Cl2>Br2>\mathrm{F}_2\gt\mathrm{Cl}_2\gt\mathrm{Br}_2\gt\mathrm{I}2_2.
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