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JIPMER 2009
Exam
JIPMER
Year
2009
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JIPMER 2009 · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Which of the following is not correct ?

Which of the following is not correct ?

Options

  1. AHydrolysis of NCl3\mathrm{NCl}_3 gives NH3\mathrm{NH}_3 and HOCl
  2. BNH3\mathrm{NH}_3 is less stable than PH3\mathrm{PH}_3
  3. CNH3\mathrm{NH}_3 is a weak reducing reagent compared to PH3\mathrm{PH}_3
  4. DNitric oxide in solid state exhibits diamagnetic property

Correct answer

B. NH3\mathrm{NH}_3 is less stable than PH3\mathrm{PH}_3

Step-by-step solution

Among V A group hydrides, the stability decreases in going down the group ie, NH3>PH3>AsH3>SbH3>BiH3\mathrm{NH}_3\gt\mathrm{PH}_3\gt\mathrm{AsH}_3\gt\mathrm{SbH}_3\gt\mathrm{BiH}_3 It is due to the increasing bond length down the group.
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