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JIPMER 2013
Exam
JIPMER
Year
2013
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JIPMER 2013 · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Which of the following is the increasing order of enthalpy of...

Which of the following is the increasing order of enthalpy of vaporization?

Options

  1. ANH3,PH3,AsH3\mathrm{NH}_3, \mathrm{PH}_3, \mathrm{AsH}_3
  2. BAsH3,PH3,NH3\mathrm{AsH}_3, \mathrm{PH}_3, \mathrm{NH}_3
  3. CNH3,AsH3,PH3\mathrm{NH}_3, \mathrm{AsH}_3, \mathrm{PH}_3
  4. DPH3,AsH3,NH3\mathrm{PH}_3, \mathrm{AsH}_3, \mathrm{NH}_3

Correct answer

D. PH3,AsH3,NH3\mathrm{PH}_3, \mathrm{AsH}_3, \mathrm{NH}_3

Step-by-step solution

The inter-particle forces are strongest in (\mathrm{NH}_3) (Hydrogen bonds). In (\mathrm{PH}_3) and (\mathrm{AsH}_3) the inter-particle forces are dipole-dipole forces which are relatively stronger in (\mathrm{AsH}_3). So the increasing order of vaporization is (\mathrm{PH}_3, \mathrm{AsH}_3), and (\mathrm{NH}_3)
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