AIIMS 2006
- Exam
- AIIMS
- Year
- 2006
- Subject
- Chemistry
- Chapter
- Chemical Bonding and Molecular Structure
AIIMS 2006 · Chemistry · Chemical Bonding and Molecular Structure
In [Ag(CN)_2]^ - , the number of π bonds is
In , the number of bonds is
Options
- A2
- B3
- C4
- D6 .
Correct answer
C. 4
Step-by-step solution
Cyanide is considered, in a broad sense, to be the most potent ligand for many transition metals. The very high affinities of metals for cyanide can be attributed to its negative charge, compactness and ability to engage in -bonding. The dicyanides \left[M(\mathrm{CN})_2\right]^{-}(M=\mathrm{Cu}, \mathrm{Ag}, \mathrm{Au})-\mathrm{C} \underset{2 \pi}{\stackrel{1 \sigma}{\equiv}} \mathrm{N}4 \pi-bonds.