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AIIMS 2006
Exam
AIIMS
Year
2006
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

AIIMS 2006 · Chemistry · Chemical Bonding and Molecular Structure

In [Ag(CN)_2]^ - , the number of π bonds is

In [Ag(CN)2]−\left[\mathrm{Ag}(\mathrm{CN})_2\right]^{-}, the number of π\pi bonds is

Options

  1. A2
  2. B3
  3. C4
  4. D6 .

Correct answer

C. 4

Step-by-step solution

Cyanide is considered, in a broad sense, to be the most potent ligand for many transition metals. The very high affinities of metals for cyanide can be attributed to its negative charge, compactness and ability to engage in π\pi-bonding. The dicyanides \left[M(\mathrm{CN})_2\right]^{-}(M=\mathrm{Cu}, \mathrm{Ag}, \mathrm{Au})arelinearingeometry.are linear in geometry.-\mathrm{C} \underset{2 \pi}{\stackrel{1 \sigma}{\equiv}} \mathrm{N}Thus,twocyanideionshaveThus, two cyanide ions have4 \pi-bonds.
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