Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
AIIMS 2014
Exam
AIIMS
Year
2014
Subject
Chemistry
Chapter
Chemical Equilibrium

AIIMS 2014 · Chemistry · Chemical Equilibrium

The equilibrium constant for the reaction, (1)/(2) H_ 2(g) +(1)/(2)...

The equilibrium constant for the reaction, 12H2(g)+12\frac{1}{2} \mathrm{H}_{2(g)}+\frac{1}{2}\mathrm{I}2(g)⇌HI(g)_{2(g)} \rightleftharpoons \mathrm{HI}_{(g)} is KcK_c. Equilibrium constant for the reaction, 2HI(g)⇌H2(g)+2 \mathrm{HI}_{(g)} \rightleftharpoons \mathrm{H}_{2(g)}+\mathrm{I}2(g)_{2(g)} will beThe equilibrium constant for the reaction, (1)/(2) H_ 2(g) +(1)/(2) I _ 2(g) leftharpoons HI_ (g) is K_c . EquilibriumThe equilibrium constant for the reaction, (1)/(2) H_ 2(g) +(1)/(2) I _ 2(g) leftharpoons HI_ (g) is K_c . EquilibriumThe equilibrium constant for the reaction, (1)/(2) H_ 2(g) +(1)/(2) I _ 2(g) leftharpoons HI_ (g) is K_c . Equilibrium

Options

  1. A1/Kc1 / K_c
  2. B1/(Kc)21 /\left(K_c\right)^2
  3. C2/Kc2 / K_c
  4. D2/(Kc)22 /\left(K_c\right)^2

Correct answer

B. 1/(Kc)21 /\left(K_c\right)^2

Step-by-step solution

The given reaction is, 12H2(g)+12\frac{1}{2} \mathrm{H}_{2(g)}+\frac{1}{2}\mathrm{I}2(g)⇌HI(g)_{2(g)} \rightleftharpoons \mathrm{HI}_{(g)}The equilibrium constant for the reaction, (1)/(2) H_ 2(g) +(1)/(2) I _ 2(g) leftharpoons HI_ (g) is K_c . Equilibrium
Hence, K_c=\frac{[\mathrm{HI}]}{\left[\mathrm{H}_2\right]^{1 / 2}\left[\mathrm{I}_2\right]^{1 / 2}}The equilibrium constant for the reaction, (1)/(2) H_ 2(g) +(1)/(2) I _ 2(g) leftharpoons HI_ (g) is K_c . Equilibrium
Now, reverse the eqn. (i) and multiply by 2 , we get 2HI⇌H2(g)+2 \mathrm{HI} \rightleftharpoons \mathrm{H}_{2(g)}+\mathrm{I}2(g)_{2(g)} Hence, K_c^{\prime}=\frac{\left[\mathrm{H}_2\right]\left[\mathrm{I}_2\right]}{[\mathrm{HI}]^2}The equilibrium constant for the reaction, (1)/(2) H_ 2(g) +(1)/(2) I _ 2(g) leftharpoons HI_ (g) is K_c . Equilibrium
Equating equations (ii) and (iii), we get $K_c^{\prime}=\frac{1}{\left(K_c\right)^2}
Practice Chemical Equilibrium on Quantrex Academy →

More from Chemical Equilibrium

For which of the following solids does solubility decrease with an increase in… MHT CET Medical 2026Given below are certain reactions. Identify the reaction for which K_p ≠ K_c : NEET 2026Higher yield of NO in N_2(~g)+O_2(~g) leftharpoons 2 NO(g) can be obtained at [ Δ H of… NEET 2025For the reaction A(g) leftharpoons 2 ~B(~g) , the backward reaction rate constant is… NEET 2025Consider the following reaction in a sealed vessel at equilibrium with concentrations of… NEET 2024For the reaction 2 ~A leftharpoons B+C, K_ C =4 × 10^ -3 . At a given time, the… NEET 2024For the reaction in equilibrium N_2(~g)+3 H_2(~g) leftharpoons 2 NH_3(~g), Δ H=-Q… NEET 2024In which of the following equilibria, K_ p and K_ c are NOT equal? NEET 2024 Full Chemical Equilibrium list All AIIMS PYQs