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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

A binary solution is prepared by mixing 2 moles of liquid P and 3...

A binary solution is prepared by mixing 2 moles of liquid P and 3 moles of liquid Q. At a certain temperature, the vapour pressures of pure P and pure Q are 120 mm Hg and 160 mm Hg, respectively. If the experimentally observed total vapour pressure of the mixture is 155 mm Hg, which of the following statements is correct regarding this solution?

Options

  1. AThe process of mixing liquids P and Q is exothermic (ΔHmix<0\Delta H_{\text{mix}} < 0).
  2. BThe solution is capable of forming a maximum boiling azeotrope.
  3. CThe intermolecular attractive forces between P and Q are weaker than those in pure P and pure Q.
  4. DThe volume of the resulting solution is less than the sum of the volumes of the unmixed liquids.

Correct answer

C. The intermolecular attractive forces between P and Q are weaker than those in pure P and pure Q.

Step-by-step solution

Mole fraction of P, xP=22+3=0.4x_P = \dfrac{2}{2+3} = 0.4

Mole fraction of Q, xQ=32+3=0.6x_Q = \dfrac{3}{2+3} = 0.6

According to Raoult's law, the ideal vapour pressure of the solution is:

Pideal=PP∘xP+PQ∘xQP_{\text{ideal}} = P_P^\circ x_P + P_Q^\circ x_Q

Pideal=120×0.4+160×0.6=48+96=144 mm HgP_{\text{ideal}} = 120 \times 0.4 + 160 \times 0.6 = 48 + 96 = 144 \text{ mm Hg}

The observed vapour pressure is 155 mm Hg155 \text{ mm Hg}, which is greater than the ideal vapour pressure (155>144155 > 144). This indicates that the solution shows a positive deviation from Raoult's law.

For a solution showing positive deviation:

1. The intermolecular attractive forces between the different molecules (P-Q) are weaker than those between the similar molecules (P-P and Q-Q).

2. ΔHmix>0\Delta H_{\text{mix}} > 0 (endothermic process).

3. ΔVmix>0\Delta V_{\text{mix}} > 0 (volume increases on mixing).

4. The solution can form a minimum boiling azeotrope.

Thus, the statement about weaker intermolecular attractive forces between P and Q is correct.

Answer: The intermolecular attractive forces between P and Q are weaker than those in pure P and pure Q.
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