NEET 2026
- Exam
- NEET
- Year
- 2026
- Subject
- Chemistry
- Chapter
- Chapter
NEET 2026 · Chemistry · Chapter
Identify the major organic product formed in the following reaction.
Identify the major organic product formed in the following reaction.
Options
- A

- B

- C

- D

Correct answer
C. 
Step-by-step solution
The reactant is a molecule containing both a ketone group ( ) and a cyano group ().
Grignard reagents () are strong nucleophiles and will react with both electrophilic centers: the carbonyl carbon and the cyano carbon.
Reaction at the ketone group: The methyl nucleophile () attacks the carbonyl carbon, opening the double bond to form a tetrahedral alkoxide intermediate. Upon acidic workup (), this alkoxide is protonated to form a tertiary alcohol. Since the original ketone has an ethyl group and a propyl chain attached, the addition of a methyl group results in a tertiary alcohol with ethyl, methyl, and the rest of the chain attached to the carbon.
Reaction at the cyano group: The methyl nucleophile () attacks the electrophilic carbon of the nitrile group, forming an imine anion intermediate (). Upon acidic hydrolysis (), this imine intermediate is converted into a ketone. The resulting ketone will have a methyl group attached to the former cyano carbon, forming a methyl ketone.
Since the Grignard reagent is in excess, both functional groups will react completely.
The ketone on the right side of the molecule becomes a tertiary alcohol (with a new methyl group added).
The cyano group on the left side of the molecule is converted to a methyl ketone.
Therefore, the final product will have a tertiary alcohol at one end and a methyl ketone at the other end. Looking at the options, structure (3) correctly shows the tertiary alcohol where the original ketone was (with a new methyl group) and the methyl ketone where the original cyano group was.
Grignard reagents () are strong nucleophiles and will react with both electrophilic centers: the carbonyl carbon and the cyano carbon.
Reaction at the ketone group: The methyl nucleophile () attacks the carbonyl carbon, opening the double bond to form a tetrahedral alkoxide intermediate. Upon acidic workup (), this alkoxide is protonated to form a tertiary alcohol. Since the original ketone has an ethyl group and a propyl chain attached, the addition of a methyl group results in a tertiary alcohol with ethyl, methyl, and the rest of the chain attached to the carbon.
Reaction at the cyano group: The methyl nucleophile () attacks the electrophilic carbon of the nitrile group, forming an imine anion intermediate (). Upon acidic hydrolysis (), this imine intermediate is converted into a ketone. The resulting ketone will have a methyl group attached to the former cyano carbon, forming a methyl ketone.
Since the Grignard reagent is in excess, both functional groups will react completely.
The ketone on the right side of the molecule becomes a tertiary alcohol (with a new methyl group added).
The cyano group on the left side of the molecule is converted to a methyl ketone.
Therefore, the final product will have a tertiary alcohol at one end and a methyl ketone at the other end. Looking at the options, structure (3) correctly shows the tertiary alcohol where the original ketone was (with a new methyl group) and the methyl ketone where the original cyano group was.