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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

Identify the major organic product formed in the following reaction.

Identify the major organic product formed in the following reaction.
Identify the major organic product formed in the following reaction.

Options

  1. AIf the error in the measurement of radius of a sphere is 2 \% , then the error in the determination of volume of the
  2. BIf the error in the measurement of radius of a sphere is 2 \% , then the error in the determination of volume of the
  3. CIf the error in the measurement of radius of a sphere is 2 \% , then the error in the determination of volume of the
  4. DIf the error in the measurement of radius of a sphere is 2 \% , then the error in the determination of volume of the

Correct answer

C. If the error in the measurement of radius of a sphere is 2 \% , then the error in the determination of volume of the

Step-by-step solution

The reactant is a molecule containing both a ketone group (−C(=O)−-C(=O)- ) and a cyano group (−C≡N-C\equiv N).

Grignard reagents (CH3MgBrCH_3MgBr) are strong nucleophiles and will react with both electrophilic centers: the carbonyl carbon and the cyano carbon.

Reaction at the ketone group: The methyl nucleophile (CH3−CH_3^-) attacks the carbonyl carbon, opening the C=OC=O double bond to form a tetrahedral alkoxide intermediate. Upon acidic workup (H3O+H_3O^+), this alkoxide is protonated to form a tertiary alcohol. Since the original ketone has an ethyl group and a propyl chain attached, the addition of a methyl group results in a tertiary alcohol with ethyl, methyl, and the rest of the chain attached to the carbon.

Reaction at the cyano group: The methyl nucleophile (CH3−CH_3^-) attacks the electrophilic carbon of the nitrile group, forming an imine anion intermediate (−C(CH3)=N−MgBr+-C(CH_3)=N^-MgBr^+). Upon acidic hydrolysis (H3O+H_3O^+), this imine intermediate is converted into a ketone. The resulting ketone will have a methyl group attached to the former cyano carbon, forming a methyl ketone.

Since the Grignard reagent is in excess, both functional groups will react completely.

The ketone on the right side of the molecule becomes a tertiary alcohol (with a new methyl group added).

The cyano group on the left side of the molecule is converted to a methyl ketone.

Therefore, the final product will have a tertiary alcohol at one end and a methyl ketone at the other end. Looking at the options, structure (3) correctly shows the tertiary alcohol where the original ketone was (with a new methyl group) and the methyl ketone where the original cyano group was.
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