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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

Observe the given structure of 1-buten-3-yne where specific bonds...

Observe the given structure of 1-buten-3-yne where specific bonds are labeled as 'a', 'b', 'c', and 'd'. Match the
Observe the given structure of 1-buten-3-yne where specific bonds are labeled as 'a', 'b', 'c', and 'd'. Match the labeled bonds in List I with their corresponding nature in List II.

List IList II
ABond 'a'IOne σ\sigma and two π\pi bonds
BBond 'b'IIOne σ\sigma bond formed by sp2−spsp^2-sp overlap
CBond 'c'IIIOne σ\sigma and one π\pi bond
DBond 'd'IVOne σ\sigma bond formed by sp−ssp-s overlap

Choose the correct answer from the options given below:

Options

  1. AA-I, B-II, C-III, D-IV
  2. BA-II, B-III, C-IV, D-I
  3. CA-III, B-IV, C-I, D-II
  4. DA-III, B-II, C-I, D-IV

Correct answer

D. A-III, B-II, C-I, D-IV

Step-by-step solution

The given molecule is 1-buten-3-yne: CH2=CH−C≡C−H\text{CH}_2=\text{CH}-\text{C}\equiv\text{C}-\text{H}.

First, determine the hybridization of each carbon atom:
The terminal carbon C1C_1 (CH2=\text{CH}_2=) is bonded to three atoms with no lone pairs, so it is sp2sp^2 hybridized.
The carbon C2C_2 (=CH−=\text{CH}-) is bonded to three atoms, so it is sp2sp^2 hybridized.
The carbon C3C_3 (−C≡-\text{C}\equiv) is bonded to two atoms, so it is spsp hybridized.
The carbon C4C_4 (≡C−H\equiv\text{C}-\text{H}) is bonded to two atoms, so it is spsp hybridized.

Now, analyze the labeled bonds:
Bond 'a' is a double bond between C1C_1 and C2C_2. A double bond consists of one σ\sigma bond and one π\pi bond. (A →\rightarrow III)
Bond 'b' is a single bond between C2C_2 (sp2sp^2)andC3and C_3 (spsp). It is a σ\sigma bond formed by the overlap of an sp2sp^2 orbital and an spsp orbital. (B →\rightarrow II)
Bond 'c' is a triple bond between C3C_3 and C4C_4. A triple bond consists of one σ\sigma bond and two π\pi bonds. (C →\rightarrow I)
Bond 'd' is a single bond between C4C_4 (spsp) and a hydrogen atom (ss). It is a σ\sigma bond formed by the overlap of an spsp orbital and an ss orbital. (D →\rightarrow IV)

Therefore, the correct matching is A-III, B-II, C-I, D-IV.

Answer: A-III, B-II, C-I, D-IV
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