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NEET2026ChemistryChapterActual

To prepare Fehling's reagent for the identification of aliphatic aldehydes, aqueous copper sulphate is mixed with an alkaline solution of a complexing agent. This agent prevents the precipitation of cupric hydroxide by forming a soluble complex. The complexing agent used is:

Options

  1. APotassium iodide
  2. BAmmonium hydroxide
  3. CSodium potassium tartrate
  4. DSodium citrate

Correct answer

C. Sodium potassium tartrate

Step-by-step solution

Fehling's reagent is prepared by mixing two solutions: Fehling's A and Fehling's B. Fehling's A is an aqueous solution of copper sulphate ( CuSO ₄ ). Fehling's B is an alkaline solution of sodium potassium tartrate, which is also known as Rochelle salt. When these two solutions are mixed, the tartrate ions act as a chelating agent and form a soluble deep blue complex with the cupric ions ( Cu ²⁺ ). This complexation prevents the precipitation of cupric hydroxide ( Cu(OH) ₂ ) in the strongly alkaline medium. Therefo

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