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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

To prepare Fehling's reagent for the identification of aliphatic...

To prepare Fehling's reagent for the identification of aliphatic aldehydes, aqueous copper sulphate is mixed with an alkaline solution of a complexing agent. This agent prevents the precipitation of cupric hydroxide by forming a soluble complex. The complexing agent used is:

Options

  1. APotassium iodide
  2. BAmmonium hydroxide
  3. CSodium potassium tartrate
  4. DSodium citrate

Correct answer

C. Sodium potassium tartrate

Step-by-step solution

Fehling's reagent is prepared by mixing two solutions: Fehling's A and Fehling's B.

Fehling's A is an aqueous solution of copper sulphate (CuSO4\text{CuSO}_4).

Fehling's B is an alkaline solution of sodium potassium tartrate, which is also known as Rochelle salt.

When these two solutions are mixed, the tartrate ions act as a chelating agent and form a soluble deep blue complex with the cupric ions (Cu2+\text{Cu}^{2+}). This complexation prevents the precipitation of cupric hydroxide (Cu(OH)2\text{Cu(OH)}_2) in the strongly alkaline medium.

Therefore, the complexing agent used is sodium potassium tartrate.

Answer: Sodium potassium tartrate
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