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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

The reaction, CF_3CH_2OH + CH_3CH_2ONa arrow CF_3CH_2ONa +...

The reaction,
CF3CH2OH+CH3CH2ONa→CF3CH2ONa+CH3CH2OH\mathrm{CF_3CH_2OH} + \mathrm{CH_3CH_2ONa} \rightarrow \mathrm{CF_3CH_2ONa} + \mathrm{CH_3CH_2OH}
suggests that:

Options

  1. Aethanol is a stronger acid than 2,2,2-trifluoroethanol
  2. B2,2,2-trifluoroethanol is a stronger acid than ethanol
  3. Cethoxide ion is a weaker base than 2,2,2-trifluoroethoxide ion
  4. Dwater is a stronger acid than 2,2,2-trifluoroethanol

Correct answer

B. 2,2,2-trifluoroethanol is a stronger acid than ethanol

Step-by-step solution

The given reaction is an acid-base reaction where CF3CH2OH\mathrm{CF_3CH_2OH} acts as an acid and CH3CH2ONa\mathrm{CH_3CH_2ONa} acts as a base.

The reaction proceeds in the forward direction, which implies that a stronger acid and a stronger base react to form a weaker acid and a weaker base.

Here, CF3CH2OH\mathrm{CF_3CH_2OH} donates a proton to the ethoxide ion (CH3CH2O−\mathrm{CH_3CH_2O^-}) to form ethanol (CH3CH2OH\mathrm{CH_3CH_2OH}).

This indicates that CF3CH2OH\mathrm{CF_3CH_2OH} (2,2,2-trifluoroethanol) is a stronger acid than CH3CH2OH\mathrm{CH_3CH_2OH} (ethanol).

The strong −I-I effect of the three fluorine atoms stabilizes the CF3CH2O−\mathrm{CF_3CH_2O^-} ion, making it a weaker base than the ethoxide ion, and consequently making 2,2,2-trifluoroethanol a stronger acid than ethanol.

Answer: 2,2,2-trifluoroethanol is a stronger acid than ethanol
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