NEET 2026
- Exam
- NEET
- Year
- 2026
- Subject
- Chemistry
- Chapter
- Chapter
NEET 2026 · Chemistry · Chapter
Consider the chemical reaction scheme shown in the given figure....
Consider the chemical reaction scheme shown in the given figure.
Which of the following statements is correct regarding the major products and ?
Options
- AProduct is methanamine and product is acetic acid.
- BBoth and are primary amines, but contains one carbon atom less than .
- C and are successive members of the same homologous series.
- DProduct gives a positive carbylamine test whereas product does not.
Correct answer
C. and are successive members of the same homologous series.
Step-by-step solution
Reaction of acetic acid with ammonia followed by heating yields acetamide.
(X)
Acetamide (X) undergoes Hoffmann bromamide degradation upon reaction with and to form a primary amine with one carbon atom less, which is methanamine.
(Y)
Acetamide (X) undergoes reduction with to form a primary amine with the same number of carbon atoms, which is ethanamine.
(Z)
Y is methanamine () and Z is ethanamine ().
Both are primary amines and differ by a unit. Therefore, they are successive members of the same homologous series.
Both Y and Z will give a positive carbylamine test since they are primary amines.
Answer: and are successive members of the same homologous series.
(X)
Acetamide (X) undergoes Hoffmann bromamide degradation upon reaction with and to form a primary amine with one carbon atom less, which is methanamine.
(Y)
Acetamide (X) undergoes reduction with to form a primary amine with the same number of carbon atoms, which is ethanamine.
(Z)
Y is methanamine () and Z is ethanamine ().
Both are primary amines and differ by a unit. Therefore, they are successive members of the same homologous series.
Both Y and Z will give a positive carbylamine test since they are primary amines.
Answer: and are successive members of the same homologous series.