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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

Consider the chemical reaction scheme shown in the given figure....

Consider the chemical reaction scheme shown in the given figure. Which of the following statements is correct regarding
Consider the chemical reaction scheme shown in the given figure.

Which of the following statements is correct regarding the major products YY and ZZ?

Options

  1. AProduct YY is methanamine and product ZZ is acetic acid.
  2. BBoth YY and ZZ are primary amines, but ZZ contains one carbon atom less than XX.
  3. CYY and ZZ are successive members of the same homologous series.
  4. DProduct ZZ gives a positive carbylamine test whereas product YY does not.

Correct answer

C. YY and ZZ are successive members of the same homologous series.

Step-by-step solution

Reaction of acetic acid with ammonia followed by heating yields acetamide.

CH3COOH→NH3,ΔCH3CONH2\text{CH}_3\text{COOH} \xrightarrow{\text{NH}_3, \Delta} \text{CH}_3\text{CONH}_2 (X)

Acetamide (X) undergoes Hoffmann bromamide degradation upon reaction with Br2\text{Br}_2 and NaOH\text{NaOH} to form a primary amine with one carbon atom less, which is methanamine.

CH3CONH2→Br2,NaOHCH3NH2\text{CH}_3\text{CONH}_2 \xrightarrow{\text{Br}_2, \text{NaOH}} \text{CH}_3\text{NH}_2 (Y)

Acetamide (X) undergoes reduction with LiAlH4\text{LiAlH}_4 to form a primary amine with the same number of carbon atoms, which is ethanamine.

CH3CONH2→(i) LiAlH4,ether (ii) H2OCH3CH2NH2\text{CH}_3\text{CONH}_2 \xrightarrow{\text{(i) LiAlH}_4, \text{ether} \text{ (ii) H}_2\text{O}} \text{CH}_3\text{CH}_2\text{NH}_2 (Z)

Y is methanamine (CH3NH2\text{CH}_3\text{NH}_2) and Z is ethanamine (CH3CH2NH2\text{CH}_3\text{CH}_2\text{NH}_2).

Both are primary amines and differ by a −CH2−-\text{CH}_2- unit. Therefore, they are successive members of the same homologous series.

Both Y and Z will give a positive carbylamine test since they are primary amines.

Answer: YY and ZZ are successive members of the same homologous series.
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