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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

The given reaction illustrates the direct iodination of...

The given reaction illustrates the direct iodination of ethylbenzene. Unlike chlorination or bromination, this reaction
The given reaction illustrates the direct iodination of ethylbenzene. Unlike chlorination or bromination, this reaction is reversible due to the formation of a strong reducing byproduct. To drive the equilibrium in the forward direction, Reagent Z is required. Identify the most suitable Reagent Z from the following.

Options

  1. AHIO4HIO_4
  2. BAnhydrous AlCl3AlCl_3
  3. CFeFe powder in dark
  4. DLiAlH4LiAlH_4

Correct answer

A. HIO4HIO_4

Step-by-step solution

Direct iodination of aromatic compounds is a reversible process because the byproduct, HIHI, is a strong reducing agent. It reduces the formed iodoarene back to the starting arene.

Ar−H+I2⇌Ar−I+HIAr-H + I_2 \rightleftharpoons Ar-I + HI

To drive the equilibrium in the forward direction, the HIHI produced must be consumed. This is achieved by carrying out the reaction in the presence of an oxidizing agent such as HIO3HIO_3, HIO4HIO_4, or HNO3HNO_3.

The oxidizing agent oxidizes HIHI to I2I_2, thereby preventing the reverse reaction and shifting the equilibrium to the right:

7HI+HIO4→4I2+4H2O7HI + HIO_4 \rightarrow 4I_2 + 4H_2O

Among the given options, HIO4HIO_4 is the only suitable oxidizing agent.

Answer: HIO4HIO_4
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