NEET 2026
- Exam
- NEET
- Year
- 2026
- Subject
- Chemistry
- Chapter
- Chapter
NEET 2026 · Chemistry · Chapter
Formic acid (methanoic acid) exhibits certain unique and abnormal...
Formic acid (methanoic acid) exhibits certain unique and abnormal behaviors compared to other higher aliphatic carboxylic acids due to its specific structure. Which of the following statements regarding formic acid is INCORRECT?
Options
- AIt acts as a reducing agent and forms a silver mirror when treated with Tollens' reagent.
- BIt gives a brick-red precipitate of when heated with Fehling's solution.
- CIt readily undergoes the Hell-Volhard-Zelinsky (HVZ) reaction when treated with and red phosphorus.
- DIt rapidly dehydrates to yield carbon monoxide () gas when heated with concentrated .
Correct answer
C. It readily undergoes the Hell-Volhard-Zelinsky (HVZ) reaction when treated with and red phosphorus.
Step-by-step solution
Formic acid () possesses a unique structure containing both an aldehydic group and a carboxylic acid group.
Due to the presence of the aldehydic moiety, it acts as a reducing agent. It reduces Tollens' reagent to form a silver mirror and Fehling's solution to form a brick-red precipitate of . Thus, statements (1) and (2) are correct.
Heating formic acid with concentrated leads to its dehydration, producing carbon monoxide () gas and water. Thus, statement (4) is correct.
The Hell-Volhard-Zelinsky (HVZ) reaction involves the halogenation of carboxylic acids at the -carbon. This reaction strictly requires the presence of at least one -hydrogen atom. Since formic acid lacks an -carbon atom, it does not contain any -hydrogen atoms and cannot undergo the HVZ reaction. Thus, statement (3) is incorrect.
Due to the presence of the aldehydic moiety, it acts as a reducing agent. It reduces Tollens' reagent to form a silver mirror and Fehling's solution to form a brick-red precipitate of . Thus, statements (1) and (2) are correct.
Heating formic acid with concentrated leads to its dehydration, producing carbon monoxide () gas and water. Thus, statement (4) is correct.
The Hell-Volhard-Zelinsky (HVZ) reaction involves the halogenation of carboxylic acids at the -carbon. This reaction strictly requires the presence of at least one -hydrogen atom. Since formic acid lacks an -carbon atom, it does not contain any -hydrogen atoms and cannot undergo the HVZ reaction. Thus, statement (3) is incorrect.