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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

Formic acid (methanoic acid) exhibits certain unique and abnormal...

Formic acid (methanoic acid) exhibits certain unique and abnormal behaviors compared to other higher aliphatic carboxylic acids due to its specific structure. Which of the following statements regarding formic acid is INCORRECT?

Options

  1. AIt acts as a reducing agent and forms a silver mirror when treated with Tollens' reagent.
  2. BIt gives a brick-red precipitate of Cu2OCu_2O when heated with Fehling's solution.
  3. CIt readily undergoes the Hell-Volhard-Zelinsky (HVZ) reaction when treated with Cl2Cl_2 and red phosphorus.
  4. DIt rapidly dehydrates to yield carbon monoxide (COCO) gas when heated with concentrated H2SO4H_2SO_4.

Correct answer

C. It readily undergoes the Hell-Volhard-Zelinsky (HVZ) reaction when treated with Cl2Cl_2 and red phosphorus.

Step-by-step solution

Formic acid (H−COOHH-COOH) possesses a unique structure containing both an aldehydic group and a carboxylic acid group.

Due to the presence of the aldehydic moiety, it acts as a reducing agent. It reduces Tollens' reagent to form a silver mirror and Fehling's solution to form a brick-red precipitate of Cu2OCu_2O. Thus, statements (1) and (2) are correct.

Heating formic acid with concentrated H2SO4H_2SO_4 leads to its dehydration, producing carbon monoxide (COCO) gas and water. Thus, statement (4) is correct.

The Hell-Volhard-Zelinsky (HVZ) reaction involves the halogenation of carboxylic acids at the α\alpha-carbon. This reaction strictly requires the presence of at least one α\alpha-hydrogen atom. Since formic acid lacks an α\alpha-carbon atom, it does not contain any α\alpha-hydrogen atoms and cannot undergo the HVZ reaction. Thus, statement (3) is incorrect.
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