NEET 2026
- Exam
- NEET
- Year
- 2026
- Subject
- Chemistry
- Chapter
- Chapter
NEET 2026 · Chemistry · Chapter
Observe the reaction sequence provided in the diagram. Identify the...
Observe the reaction sequence provided in the diagram.
Identify the final major product .
Options
- Atert-Butylbenzene
- BBenzene
- Cp-tert-Butylphenol
- DToluene
Correct answer
A. tert-Butylbenzene
Step-by-step solution
The starting material is p-tert-butyltoluene.
In the first step, the reaction with alkaline followed by acidification () is an oxidation of alkylbenzenes. Alkyl groups attached to a benzene ring that possess at least one benzylic hydrogen are oxidized to a carboxylic acid () group.
The methyl group () has three benzylic hydrogens and is oxidized to a group. The tert-butyl group () lacks benzylic hydrogens and is resistant to oxidation. Therefore, product A is p-tert-butylbenzoic acid.
In the second step, heating product A with sodalime () results in decarboxylation. The group is removed as (forming ) and replaced by a hydrogen atom.
Thus, the final major product B is tert-butylbenzene.
Answer: tert-Butylbenzene
In the first step, the reaction with alkaline followed by acidification () is an oxidation of alkylbenzenes. Alkyl groups attached to a benzene ring that possess at least one benzylic hydrogen are oxidized to a carboxylic acid () group.
The methyl group () has three benzylic hydrogens and is oxidized to a group. The tert-butyl group () lacks benzylic hydrogens and is resistant to oxidation. Therefore, product A is p-tert-butylbenzoic acid.
In the second step, heating product A with sodalime () results in decarboxylation. The group is removed as (forming ) and replaced by a hydrogen atom.
Thus, the final major product B is tert-butylbenzene.
Answer: tert-Butylbenzene