NEET 2026
- Exam
- NEET
- Year
- 2026
- Subject
- Chemistry
- Chapter
- Chapter
NEET 2026 · Chemistry · Chapter
Observe the given reaction scheme showing various methods for the...
Observe the given reaction scheme showing various methods for the preparation of benzaldehyde. Match the pathways labelled P, Q, R, and S in List I with their corresponding reaction names or types in List II.
| List I | List II | ||
|---|---|---|---|
| A | Pathway P | 1 | Etard reaction |
| B | Pathway Q | 2 | Side-chain chlorination |
| C | Pathway R | 3 | Rosenmund reduction |
| D | Pathway S | 4 | Stephen reaction |
Choose the correct answer from the options given below.
Options
- A(A)-(4), (B)-(3), (C)-(2), (D)-(1)
- B(A)-(3), (B)-(4), (C)-(1), (D)-(2)
- C(A)-(3), (B)-(4), (C)-(2), (D)-(1)
- D(A)-(1), (B)-(2), (C)-(3), (D)-(4)
Correct answer
B. (A)-(3), (B)-(4), (C)-(1), (D)-(2)
Step-by-step solution
Pathway P: The reduction of benzoyl chloride to benzaldehyde using in the presence of is known as the Rosenmund reduction. Thus, A 3.
Pathway Q: The reduction of benzonitrile to benzaldehyde using and followed by acidic hydrolysis is known as the Stephen reaction. Thus, B 4.
Pathway R: The oxidation of toluene to benzaldehyde using chromyl chloride () is known as the Etard reaction. Thus, C 1.
Pathway S: The reaction of toluene with in the presence of sunlight () yields benzal chloride, which upon hydrolysis gives benzaldehyde. This is a side-chain chlorination reaction. Thus, D 2.
The correct matching is (A)-(3), (B)-(4), (C)-(1), (D)-(2).
Answer: (A)-(3), (B)-(4), (C)-(1), (D)-(2)
Pathway Q: The reduction of benzonitrile to benzaldehyde using and followed by acidic hydrolysis is known as the Stephen reaction. Thus, B 4.
Pathway R: The oxidation of toluene to benzaldehyde using chromyl chloride () is known as the Etard reaction. Thus, C 1.
Pathway S: The reaction of toluene with in the presence of sunlight () yields benzal chloride, which upon hydrolysis gives benzaldehyde. This is a side-chain chlorination reaction. Thus, D 2.
The correct matching is (A)-(3), (B)-(4), (C)-(1), (D)-(2).
Answer: (A)-(3), (B)-(4), (C)-(1), (D)-(2)