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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Chapter

NEET 2026 · Chemistry · Chapter

London dispersion forces are the primary intermolecular forces...

London dispersion forces are the primary intermolecular forces present in non-polar molecules. Arrange the following hydrocarbons in the increasing order of the magnitude of London dispersion forces between their molecules:

(a) 2,2-Dimethylbutane
(b) n-Butane
(c) n-Hexane
(d) 2-Methylpropane
(e) n-Pentane

Choose the correct answer from the options given below:

Options

  1. A(b) << (d) << (e) << (c) << (a)
  2. B(d) << (b) << (a) << (e) << (c)
  3. C(d) << (b) << (e) << (a) << (c)
  4. D(c) << (a) << (e) << (b) << (d)

Correct answer

C. (d) << (b) << (e) << (a) << (c)

Step-by-step solution

London dispersion forces depend on the molecular mass and the surface area of the molecules. The magnitude of these forces increases with an increase in molecular mass due to higher polarizability.

The molecular formulas of the given hydrocarbons are:
(a) 2,2-Dimethylbutane: C6H14C_6H_{14}
(b) n-Butane: C4H10C_4H_{10}
(c) n-Hexane: C6H14C_6H_{14}
(d) 2-Methylpropane: C4H10C_4H_{10}
(e) n-Pentane: C5H12C_5H_{12}

Based on molecular mass, the general order of dispersion forces is C4H10<C5H12<C6H14C_4H_{10} < C_5H_{12} < C_6H_{14}.

For isomers having the same molecular mass, branching decreases the surface area of the molecule, which weakens the London dispersion forces.

Comparing the C4H10C_4H_{10} isomers, 2-methylpropane is branched while n-butane is a straight chain. Thus, the forces are weaker in 2-methylpropane: (d) << (b).

Comparing the C6H14C_6H_{14} isomers, 2,2-dimethylbutane is highly branched while n-hexane is a straight chain. Thus, the forces are weaker in 2,2-dimethylbutane: (a) << (c).

Combining these observations, the increasing order of the magnitude of London dispersion forces is (d) << (b) << (e) << (a) << (c).

Answer: (d) << (b) << (e) << (a) << (c)
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