Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE MainChemistryThermodynamics (C)

The standard enthalpy of combustion of liquid cyclopentane ( C ₅ H ₁₀ ) is -3290 kJ mol ⁻¹ . Given that the standard enthalpies of formation of CO ₂ (g) and H ₂ O(l) are -394 kJ mol ⁻¹ and -286 kJ mol ⁻¹ respectively, the standard enthalpy of formation of liquid cyclopentane is

Options

  1. A-6690 kJ mol ⁻¹
  2. B+2610 kJ mol ⁻¹
  3. C-110 kJ mol ⁻¹
  4. D+110 kJ mol ⁻¹

Correct answer

C. -110 kJ mol ⁻¹

Step-by-step solution

First, write the balanced chemical equation for the complete combustion of liquid cyclopentane: C ₅ H ₁₀ (l) + 15 2 O ₂ (g) 5 CO ₂ (g) + 5 H ₂ O(l) The standard enthalpy of combustion is related to the standard enthalpies of formation by the equation: H_ c = H_ f ( products ) - H_ f ( reactants ) H_ c = [5 H_ f ( CO ₂) + 5 H_ f ( H ₂ O )] - [ H_ f ( C ₅ H ₁₀) + 15 2 H_ f ( O ₂)] Since the standard enthalpy of formation of an element in its standard state (like O ₂ ) is zero: -3290 = [5(-394) + 5(-286)] - H_ f ( C ₅

Practice Thermodynamics (C) on Quantrex Academy →

More from Thermodynamics (C)

An ideal gas ( 0.5 mol), initially at 2 bar pressure, is compressed at a constant temperature of 600 K in two steps: first, against a constant external pressure of P bar ( 2 < P < 2026List-I contains various physical/chemical processes, and List-II contains combinations of changes in enthalpy ( H ) and entropy ( S ). Match each entry in List-I to the appropriate 2026Consider the reaction 2 H ₂ S (g) + 3 O ₂(g) 2 H ₂ O (l) + 2 SO ₂(g) The magnitude of enthalpy change for the reaction in kJ mol ⁻¹ is ________. (Nearest integer) Given: _fH^ ( H ₂ 2026Match List - I with List - II. Given V₁ and V₂ are initial and final volumes respectively. List - I (Isothermal process) List - II (Expression) A. Reversible expansion I. q = 0 B. 2026Arrange the following isothermal processes in order of the magnitude of the work ( p - V ) involved between states 1 and 2 . A. Expansion in single stage w_A B. Expansion in multi 2026Consider the reaction X Y at 300 K. If H^ and K are 28.40 kJ mol ⁻¹ and 1.8 10⁻⁷ at the same temperature, then the magnitude of S^ for the reaction in J K ⁻¹ mol ⁻¹ is _______. (Ne 2026Consider the following data for the reaction X₂(g) + Y₂(g) 2XY(g) at 600 K . The _r G^ (in kJ mol ⁻¹ ) for the reaction is : Compound _f H^ _ 600K (kJ mol ⁻¹ ) S^ _ 600K (J mol ⁻¹ 2026The correct order of molar heat capacities measured at 298 K and 1 bar is : 2026 Full Thermodynamics (C) list All JEE Main PYQs